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| Effects of Anions and Cations on π-Complexation Between Olefin and Metal Halide | |
| 作者姓名： | ZHOU Jin-xia ZHANG Yong-chun and GUO Xin-wen * State Key Laboratory of Fine Chemical Dalian University of Technology Dalian P. R. China |
| 作者单位： | ZHOU Jin-xia，ZHANG Yong-chun and GUO Xin-wen * State Key Laboratory of Fine Chemical，Dalian University of Technology，Dalian 116012，P. R. China |
| 摘 要： | Introduction Separation,recoveryofolefinorremovalof tracequantitiesofolefinfromitsmixturesbyusing π-complexatonisamostpromisingsolution,com- paredwithenergy-intensivedistillationorotheral- ternatives.π-Complexationisasubgroupofchemi- calcomplexationwhereamixtureisbroughtinto contactwithasecondphasecontainingacomplex- ingagent1].Forexample,theadsorbentscontain- ingAg+orCu+canselectivelyadsorbolefinfroman ethylene/ethaneorpropylene/propanemixture. Becausetheπ-complexationbondsarestronger th… |
| 关 键 词： | Ag^＋ C2H4 Cl^- |
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