Fourier-transform spectroscopy of NNO in the 3800-9000 cm region and global modeling of its absorption spectrum |
| |
| Authors: | H-Y Ni VI Perevalov A-W Liu S-M Hu |
| |
| Institution: | a Department of Chemical Physics, Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, No. 96, Jin Zhai Lu Road, Hefei, Anhui 230026, China
b Laboratory of Theoretical Spectroscopy, Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, Akademicheskii av. 1, 634055 Tomsk, Russia |
| |
| Abstract: | The absorption spectrum of 14N15N16O-enriched sample of nitrous oxide has been recorded at Doppler limited resolution with a Fourier-transform spectrometer in the spectral range 3500-9000 cm−1. More than 12 000 transitions of 14N15N16O were observed and ro-vibrationally assigned on the basis of the global effective Hamiltonian model. The band-by-band analysis led to the determination of the ro-vibrational parameters of a total of 107 bands. Among the 107 bands, 80 are newly observed, for 27 others the rotational analysis is significantly extended and improved. The effective Hamiltonian parameters are determined from global fitting to the observed line positions presented in this paper and collected from the literature. As a result, a set of 117 obtained effective Hamiltonian parameters reproduces 16 134 observed line positions of 148 bands with RMS of 0.0014 cm−1. |
| |
| Keywords: | Nitrous oxide Infrared Fourier-transform spectroscopy Line position Spectroscopic parameters Global model |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
