| Synthesis and Crystal Structure of a Manganese Coordination Polymer [（phen）MnCl2]n |
| |
| 引用本文： | 王文国,张晓峰,陈昌能,刘秋田.Synthesis and Crystal Structure of a Manganese Coordination Polymer [（phen）MnCl2]n[J].结构化学,2005,24(9):1088-1090. |
| |
| 作者姓名： | 王文国 张晓峰 陈昌能 刘秋田 |
| |
| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
| |
| 基金项目： | Supported by NNSFC (No. 30170229 and 20271061) |
| |
| 摘 要： | 1 INTRODUCTION Polymeric manganese complexes with fascinating topological chemistry have received considerable interest1, 2]. The complexation of phen with man- ganese ion gives rise to a wide variety of coordi- nation complexes; however, (phen)Mn coordina- tion polymers are rare since the chelation of phen results in 1 to 3 5-membered chelating rings, ob- structing the way towards the coordination poly- mer. Similar situation has also been observed for 2,2?-bipyridine (bpy) which has si…
|
| 关 键 词： | 锰 聚合体 水晶结构 合成工艺 菲咯啉 |
Synthesis and Crystal Structure of a Manganese Coordination Polymer [(phen)MnCl2]n |
| |
| WANG Wen-guo,ZHANG Xiao-Feng,CHEN Chang-Neng,LIU Qiu-Tian.Synthesis and Crystal Structure of a Manganese Coordination Polymer [(phen)MnCl2]n[J].Chinese Journal of Structural Chemistry,2005,24(9):1088-1090. |
| |
| Authors: | WANG Wen-guo ZHANG Xiao-Feng CHEN Chang-Neng LIU Qiu-Tian |
| |
| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
| |
| Abstract: | A manganese coordination polymer (phen)MnCl2]n (phen = 1,10-phenanthroline,C12H8N2) with formula C12H8Cl2MnN2 and Mr = 306.04 has been synthesized and structurally characterized by single-crystal X-ray diffraction. The crystal is of monoclinic, space group C2/c with a = 17.2451(10), b = 10.4431(8), c = 7.0349(5) (A),β= 111.983(1)°, V= 1174.82(14) (A)3, Z = 4,Dc= 1.730 g/cm3,μ = 1.552 mm-1, F(000) = 612, T= 293(2) K, R = 0.0343 and wR = 0.0877 for 826 observed reflections with I ＞ 2σ(Ⅰ). The title compound possesses a one-dimensional chain structure composed of polymeric (phen)MnCl2 units in which the manganese (Ⅱ) ion is chelated by one phen and bridged by double chloro-ligands with the Mn-N distance of 2.257(3) (A) and Mn-Clof 2.4775(8) and 2.6568(7) (A). The Mn…Mn separation is 3.853 (A). |
| |
| Keywords: | manganese complex crystal structure 1 10-phenanthroline |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
