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The effect of a constant number of particles on the pair correlation function and the density profile in a one-dimensional lattice gas
Authors:A. Ciach
Affiliation:(1) Institute of Physical Chemistry of the Polish Academy of Sciences, 01-224 Warsaw, Poland
Abstract:A one-dimensional lattice gas (Ising model) of lengthL and with nearest-neighbor couplingJ is considered in a canonical ensemble with fixed number of particlesN=L/2. Exact expressions and asymptotic forms for largeL are derived for the density-density correlation function, using periodic boundary conditions, and for the density (magnetization) profile, using antisymmetric boundary conditions. The density-density correlation function,g, assumes for temperaturesT> T, withT = 2J(kappaBlnL)–1 and forL large, the formg(x) =ggc(x) +BL–1 +a(x)L–1 +O(L–2) wherex is a distance between considered lattice sites,B is known from earlier work of Lebowitz and Percus,(1b) anda(x) decays exponentially forx rarr infin. For TlesTprime, the correlation function and the density profile behave differently, the latter exhibiting a step in the middle of the interface.
Keywords:One-dimensional lattice gas  canonical ensemble  density profile  correlation function
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