The effect of a constant number of particles on the pair correlation function and the density profile in a one-dimensional lattice gas |
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Authors: | A. Ciach |
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Affiliation: | (1) Institute of Physical Chemistry of the Polish Academy of Sciences, 01-224 Warsaw, Poland |
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Abstract: | A one-dimensional lattice gas (Ising model) of lengthL and with nearest-neighbor couplingJ is considered in a canonical ensemble with fixed number of particlesN=L/2. Exact expressions and asymptotic forms for largeL are derived for the density-density correlation function, using periodic boundary conditions, and for the density (magnetization) profile, using antisymmetric boundary conditions. The density-density correlation function,g, assumes for temperaturesT> T, withT = 2J(BlnL)–1 and forL large, the formg(x) =ggc(x) +BL–1 +a(x)L–1 +O(L–2) wherex is a distance between considered lattice sites,B is known from earlier work of Lebowitz and Percus,(1b) anda(x) decays exponentially forx . For TT, the correlation function and the density profile behave differently, the latter exhibiting a step in the middle of the interface. |
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Keywords: | One-dimensional lattice gas canonical ensemble density profile correlation function |
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