Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O |
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| Authors: | Hong-wu Xu Lin Pin Jin-xia Li Zhong-ning Chen and Ji-gui Wu |
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| Institution: | (1) Department of Materials and Chemical Engineering, ZhongYuan University of Technology, Zhengzhou, Henan, 450007, P. R. China;(2) Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China;(3) Department of Chemistry, Lanzhou University, Lanzhou, Gansu, 73000, P. R. China |
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| Abstract: | A novel heterohexanuclear complex Ni2Ag4(μ-dppm)4(pymt)6](SbF 6)2 · 2DMF · H2O (1), was synthesized by self-assembly with Ag2(μ-dppm)2(MeCN)2](SbF6) 2 and Et4N]Ni(pymt)3] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis,
1H-NMR spectrum, 31P-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis. |
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