(Nd1－xErx)2Co15.5V1.5的结构转变与磁性

利用电弧熔炼制备了(Nd1-xErx)2Co15.5V1.5（x=0—1.0）化合物样品.通过x射线衍射分析和磁性测量研究了Er替代Nd2Co15.5V1.5中的Nd时对化合物结构和磁性的影响.研究结果表明，低Er含量（x<0.4），化合物为Th2Zn17型结构；高Er含量时(x>0.)，化合物转变为Th2Ni17结构；Er含量为x＝0.4和0.5时，两种结构共存.两种结构的晶胞参数a,c和晶胞体积V随着Er含量的增加都呈现递减的趋势.随着Er含量的增加，(Nd1-xErx)2Co15.5V1.5化合物的关键词：(Nd1-xErx)2Co15.5V1.5结构转变磁性

Structure transition and magnetic properties of ( Nd1-x Erx)2 Co15.5 V1.5 compounds

Structure and magnetic properties of (Nd1-xErx)2Co15.5V1.5compounds have been investigated by means of x-ray diffraction and magnetic measurements. The results obtained show that the (Nd1-xErx)2Co15.5V1.5 compounds crystallize in the Th2Zn17type structure for lower Er content(x<0.4) and Th2Ni17type structure for higher Er content(x>0.5). The two structures coexist in the samples with x=0.4 and 0.5 The lattice constants a and c, and the unit cell volumeV show a decreasing tendency with increasing Er content in both structures. With increasing Er content, at room temperature, the anisotropy of the (Nd1-xErx)2Co15.5V1.5 compounds changes from the easy cone type for low Er content(x<0.4) to the easy axis type for higher Er content(x>0.5). The spin reorientation transition is observed for the compounds with x=0.0—0.5, and the spin reorientation temperature Tsr shows a decreasing tendency with increasing Er content. In addition, the Curie temperature TC and saturation magnetization Ms also decrease monotonically with the Er substitution for Nd in (Nd1-xErx)2Co15.5V1.5 compounds.