Selective transannular ring transformations in azirino-fused eight-membered O,N- or S,N-heterocycles |
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| Authors: | Khlebnikov Alexander F Novikov Mikhail S Shinkevich Ekaterina Yu Vidovic Denis |
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| Affiliation: | Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, 198504, St. Petersburg, Petrodvorets, Russia. Alexander.Khlebnikov@pobox.spbu.ru |
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| Abstract: | The first examples of transannular ring transformations in azirino-fused eight-membered O,N- or S,N-heterocycles involving selective aziridine ring opening and medium-sized ring contraction are described, which provide an access to functionalized 1,4-benzox(thi)azines or 1,3-benzox(thi)azoles. |
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