Hexaazaphenalenyl anion revisited: a highly symmetric planar pi system with multiple-networking ability for self-assembled metal complexation |
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Authors: | Suzuki Shuichi Morita Yasushi Fukui Kozo Sato Kazunobu Shiomi Daisuke Takui Takeji Nakasuji Kazuhiro |
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Institution: | Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. |
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Abstract: | The hexaazaphenalenyl anion (HAP, 3-), a highly symmetric heterocyclic pi system, has been synthesized and characterized. The crystal structures of its potassium salt K+.3- and copper complex Cu2+.(NH3)4.(3-)2 show pi-pi stacking and radially extended hydrogen bonds as well as coordination bonds constructed by the HAP anion. These in-plane and out-of-plane strong interactions demonstrate the multiple-networking ability of the HAP anion. |
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