Nature of solvation effects and mechanism of heterolysis of tert-alkyl halides |
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Authors: | G. F. Dvorko E. A. Ponomareva N. E. Ponomarev V. V. Zaliznyi I. V. Koshchii |
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Affiliation: | (1) Kiev Polytechnic Institute, pr. Peremogi 37, Kiev, 03056, Ukraine |
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Abstract: | Specificities of heterolysis of tert-alkyl halides in protic and aprotic solvents were analyzed. Values of log k 25 for heterolysis of tert-butyl chloride, tert-butyl bromide, tert-butyl iodiede, 1-chloro-1-methylcyclopentane, 1-chloro-1-methylcyclohexane, 1-bromo-1-methylcyclopentane, 1-bromo-1-methylcyclohexane, 2-chloro-2-phenylpropane, 1-iodoadamantane, and 2-bromo-2-methyladamantane in 19 to 44 solvents, determined mostly by the verdazyl technique were collected. Correlation analysis of solvation effects was performed in terms of multiparameter equations based on the linear free energy relationship principle, as well as in the logk-E T coordinates. The nature of solvation effects and mechanism of heterolysis of a covalent C-Hlg bond were discussed. |
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