Synthesis and characteristics of novel pentanuclear complexes [(OC)3Mn(η1,η5-C5H4)Fe(CO)2(η1,η5-C5H4CO2)]2M(η5-C5H5)2 (M=Ti, Zr) |
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| Authors: | T Yu Orlova Yu S Nekrasov P V Petrovskii M G Ezernitskaya B V Lokshin M Kh Minacheva L A Strunkina O L Lependina T V Magdesieva S V Milovanov K P Butin |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, Vorob'evy Gory, 119899 Moscow, Russian Federation |
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| Abstract: | The reaction of Cp2MCl2 complexes (M=Ti and Zr) with 2 equiv. of (OC)3Mn(η1,η5-C5H4)Fe(CO)2(η5-C5H4COONa) results in the formation of the pentanuclear complexes (OC)3Mn(η1,η5-C5H4)Fe(CO)2(η5-C5H4CO2)]2M(η5-C5H5)2, which are characterized by IR and1H NMR spectroscopy and cyclic voltammetry.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1055–1058, May, 1997. |
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| Keywords: | Group IV metal polynuclear complex synthesis IR spectra electrochemistry |
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