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ChemInform Abstract: Hexatellurium Rings in Coordination Polymers and Molecular Clusters: Synthesis and Crystal Structures of [M(Te6)]X3 (M: Rh,Ir; X: Cl,Br, I) and [Ru2(Te6)] (TeBr3)4(TeBr2)2.
Authors:Anja Guenther  Michael Ruck
Abstract:Black crystals of [Rh(Te6)]Br3 (I), [Rh(Te6)]I3 (II), [Ir(Te6)]Cl3 (III), [Ir(Te6)]Br3 (IV), and [Ir(Te6)]I3 (V) are prepared from stoichiometric mixtures of Rh or Ir, Te, and TeX4 (X: Cl, Br, I; evacuated silica tube, 300—350 °C, 7 d).
Keywords:structure (solids and liquids)  rhodium, Rh  iridium, Ir  tellurium, Te  halogens
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