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Chromium(VI) oxide-catalysed oxidations by tert-butyl hydroperoxide using benzotrifluoride as solvent
Affiliation:1. Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 1H9, Canada;2. Department of Catalyst, Iran Polymer and Petrochemical Institute (IPPI), P.O. Box 14965/115, Tehran, Iran;3. Department of Polymer Engineering, Amirkabir University of Technology, P.O. Box 15785, Tehran, Iran;4. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, P.O. Box 91775, Mashhad, Iran;1. College of Biological, Chemical Sciences and Engineering, Jiaxing University, No. 118, Jiahang Road, Jiaxing 314001, PR China;2. School of Chemistry, Nanchang University, No. 999, Xuefu Road, Nanchang 330031, PR China;1. Sorbonne Universités, UPMC Université Paris 06, UMR 8234, Phenix, 75005 Paris, France;2. TOTAL E&P, Avenue Larribau, 64018 Pau Cedex, France;1. Department of Chemistry, National Institute of Technology, Rourkela 769008, Odisha, India;2. Department of Basic Sciences, Parala Maharaja Engineering College, Sitalapalli, Brahmapur, Odisha 761003, India;3. Central Scientific Instruments Organisation (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India;4. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India;5. Institute of Chemistry of New Materials, University of Osnabrück, Barbarastrasse 7, 49067 Osnabrück, Germany;6. Institute of Chemistry, University of Bialystok, Ciolkowskiego 1K, 15-245 Bialystok, Poland
Abstract:Chromium(VI) oxide-catalysed oxidations of alcohols and activated methylenes by aqueous tert-butyl hydroperoxide have been studied using benzotrifluoride as solvent. Comparisons with previous studies showed that this solvent is a valuable alternative to methylene chloride for such reactions. © 2000 Académie des sciences / Éditions scientifiques et medicales Elsevier SAS
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