New reactions of beta-diketiminatolanthanoid complexes: sterically induced self-deprotonation of beta-diketiminato ligands |
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| Authors: | Hitchcock Peter B Lappert Michael F Protchenko Andrey V |
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| Institution: | The Chemistry Department, University of Sussex, Brighton, UKBN1 9QJ. |
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| Abstract: | Attempted synthesis of sterically demanding bis- or tris-beta-diketiminato complexes of lanthanoids resulted in ligand deprotonation and the formation of complexes containing both a "normal" and a deprotonated ligand; one of these on protonation gave the first cationic beta-diketiminato-Ln complex. |
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