Kinetics of oxidation of some disaccharides in ammoniacal medium |
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| Authors: | KC Gupta Anita Sharma VD Misra |
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| Institution: | Chemistry Department, University of Lucknow, Lucknow 226007, India |
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| Abstract: | Kinetics of oxidation of lactose, maltose, cellobiose and melibiose has been studied by hexacyanoferrate(III) in the presence of ammonia. A general mechanism involving the formation of intermediate enodiol anion has been suggested. The effects of dielectric constant and salts have been studied in detail. The oxidation products have been characterised by descending paper chromatography. Compensation effects have been observed. |
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