Propellanes—LIII : The -ene reaction of olefinic propellanes with singlet oxygen |
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Authors: | Iman Landheer David Ginsburg |
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Affiliation: | Department of Chemistry, Israel Institute or Technology, Haifa, Israel |
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Abstract: | The -ene reactions of propellanes containing an anhydride ring or a methylimide ring undergo secondary orbital control. In attack by 1O2 only the syn-products are obtained. In the corresponding lactone or ether steric hindrance plays a more important role in the direction of attack. |
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