Nitro compounds as alkylating reagents in friedel-crafts conditions : Reaction of 2-nitropropane with benzene |
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| Authors: | V Bonvino G Casini M Ferappi GM Cingolani BR Pietroni |
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| Institution: | Istituto di Chimica Farmaceutica e Tossicologica Università di Bari, Via Amendola 173, 70126 Bari, Italy;Istituto di Chimica Farmaceutica e di Chimica Organica, Università di Camerino, Italy |
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| Abstract: | Friedel-Crafts reaction of benzylic or tertiary nitro compounds with benzene gave normal alkylation products. Similarly, 2-nitropropane (2-NP) gave cumene (1) which underwent further transformation affording a mixture whose behaviour with time was investigated : results were consistent with oxidative formation of the cumyl carbonium ion (7'). |
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