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Reaction of diazonium salts with transition metals—III: Palladium(0)-catalyzed arylation of unsaturated compounds with arenediazoium salts
Authors:K Kikukawa  K Nagira  F Wada  T Matsuda
Institution:Department of Organic Synthesis, Faculty of Engineering, Kyushu University, Hakozaki, Higashiku, Fukuoka812, Japan
Abstract:Palladium (0) catalyzed reactions of arenediazonium salts for arylation of aliphatic and cyclic olefins and allylic alcohols, styrene and ethyl acrylate were studied. Effects of the olefinic compounds and other reaction variables on the arylation were presented. Arylpalladium species was proposed as the most plausible intermediated in this reaction.
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