The synthesis of functionalized cis'-bicyclo ¦3.3.0¦octanes |
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Authors: | Paul Callant Hugo De Wilde Maurits Vandewalle |
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Institution: | State University of Ghent, Department of Organic Chemistry, Laboratory for Organic Synthesis, Krijgslaan, 271 (S.4), B-9000 Gent, Belgium |
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Abstract: | A number of polyfunctionalized cis-bicycio ¦3.3.0¦octanes have been synthesized starting from the tricyclic key intermediate which was obtained by the intramolecular cyclopropanation reaction of the diazo keto ester . Selected stereocontrolled transformations of using nucleophiles and electrophiles have been studied for the preparation of the title compounds. |
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