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The conformation of succinic acid in aqueous solution studied by 1h and 13c nmr
Authors:MTeresa Nunes  Victor MS Gil  J Ascenso
Institution:Sector de Química, Lab. Nac. Engenharia e Tecnologia Industrial, Sacavém, Portugal;Department of Chemistry, University of Aveiro, Portugal;Centro de Química Estrutural, Instituto Superior Técnico, Lisboa, Portugal
Abstract:The vicinal H-H coupling constants of succinic acid were obtained as a function of pH and related to its conformation. The syn-clinal arrangement of the two CO2H groups appears as more stable than the anti-periplanar conformation at variance with previous work but in agreement with recent data on similar molecules. The vicinal13CO2H-1H coupling constant was also obtained and is found to support that conclusion. The analysis was extended to solvents of variable dielectric constant and no significant effect was found.
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