Decomposition de l'acide peroxydodecanoique dans CCl4 : role du solvant |
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| Authors: | J. Sorba J. Fossey D. Lefort J.Y. Nedelec |
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| Affiliation: | Groupe de recherches No. 12 C.N.R.S., 2 rue Henri Dunant, 94320 Thiais, France |
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| Abstract: | The decomposition of peroxydodecanoic and in refluxing CCl4 proceeds by a complex process involving ionic and radical reactions. In the latter, this study has confirmed the important role, shown previously,1 of the character(nucleophilic or electrophilic) of the radical on the regioselectivity of the attack on the peracid. |
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