Self-assembly and characterization of hydrogen-bond-induced nanostructure aggregation. |
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| Authors: | Yang Liu Junpeng Zhuang Huibiao Liu Yuliang Li Fushen Lu Haiyang Gan Tonggang Jiu Ning Wang Xiaorong He Daoben Zhu |
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| Affiliation: | CAS Key Laboratory of Organic Solidsm Center for Molecular Sciences, Institute of Chemistry Chinese Academy of Sciences, Beijing 100080 PR, China. |
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| Abstract: | A supramolecular system of a perylene derivative containing bis(2,6-diacylaminopyridine) units and a perylene bisimide bound through three hydrogen-bonds was synthesized and characterized. 1H NMR spectra confirmed the existence of hydrogen-bonding interactions between the perylene derivative (3) and the perylene bisimide (7). The photocurrent generation of the self-assembled 3.7 film was measured, and a cathodic photocurrent response was obtained. SEM images indicated that well-defined long fibers could be fabricated by self-assembly, by exploiting the hydrogen bonding interactions and pi-pi stacking interactions of perylene rings. |
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| Keywords: | aggregation hydrogen bonds nanostructures perylene bisimides self‐assembly |
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