| 镜煤吡啶不溶物及其热解加氢产物的NMR研究 |
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| 引用本文： | 杨保联 张蓬州. 镜煤吡啶不溶物及其热解加氢产物的NMR研究[J]. 波谱学杂志, 1994, 11(2): 119-126 |
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| 作者姓名： | 杨保联 张蓬州 |
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| 作者单位： | 1. 中国科学院武汉物理所波谱与原子分子国家重点实验室, 武汉 430071;2. 中国科学院山西煤炭化学研究所, 太原 030001 |
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| 摘 要： | 本文对镜煤吡啶不溶物、热解加氢后吡啶及四氢呋喃不溶物进行了固体NMR研究,获得了12种结构参数,并对热解加氢产物中的苯可溶各馏份进行了一维、二维液体NMR研究,归属了其13C和1H谱,计算了各馏份的平均分子结构.
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| 关 键 词： | 镜煤 吡啶不溶 热解加氢 NMR 平均分子结构 |
| 收稿时间： | 1993-05-17 |
NMR STUDIES OF PYRIDINE -ENSOLUBLE SOLID OF VIBRAIN AND ITS HYDROCRACKING PRODUCTS |
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| Yang Baolian,Li Liyun,Ye Chaohui,Zhang PengZhou,Xu Xiufeng. NMR STUDIES OF PYRIDINE -ENSOLUBLE SOLID OF VIBRAIN AND ITS HYDROCRACKING PRODUCTS[J]. Chinese Journal of Magnetic Resonance, 1994, 11(2): 119-126 |
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| Authors: | Yang Baolian Li Liyun Ye Chaohui Zhang PengZhou Xu Xiufeng |
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| Affiliation: | 1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wulian Institute of Physica, The Chinese Academy or Sciences, Wuhan 430071;2. Shanxi Institute of Coal Chemistry, The Chinese Academy of Sciences, Taiyuan 030001 |
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| Abstract: | Pyridine -insoluble、THF-insoluble solids of bydrocrachng products of vitrain pyridine-insoluble solid and itself were investigated by solid state 13C CP/MAS NMR technique.From the measurements, twelve structural parameters of carbon skeleton were obtained Benzene-soluble subfraction of hydrocracking products were investigated by one and two dimensions 1H and 13C liquid NMR techniques.Their 1H and 13C spectra were assigned.The avcrage molecular structures of these fractionswere obtained. |
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| Keywords: | Vitrain Pridine-insoluble Hydrocracking NMR Average molecular structure |
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