| Hydrothermal Synthesis and Structure of a Novel Two-dimensional Complex:[Ni_(0.5)(H_2O)_(1.5){Ni(en)_2}_3V_(18)O_(42)(Cl)]3.5H_2O |
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| 作者姓名： | 郑寿添 杨国昱 |
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| 作者单位： | ZHENG Shou-Tiana YANG Guo-Yua，b② a (State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China) b (State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing，Jiangsu 210093，China) |
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| 基金项目： | This work was supported by NNSFC (No. 20271050 and 20171045)，the Educational Ministry of China，the Talents Program of the Chinese Academy of Sciences and NSF of Fujian province (E0210029) |
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| 摘 要： | 1 INTRODUCTION The crystal engineering of inorganic-organic hybrid materials has generated significant interest in their new structural architectures and potential ap- plications in the fields of photochemistry, catalysis, electromagnetism and sorption1…
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Hydrothermal Synthesis and Structure of a Novel Two-dimensional Complex:[Ni0.5(H2O)1.5{Ni(en)2}3V18O42(Cl)]·3.5H2O |
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| ZHENG Shou-tian,YANG Guo-Yu.Hydrothermal Synthesis and Structure of a Novel Two-dimensional Complex:[Ni_(0.5)(H_2O)_(1.5){Ni(en)_2}_3V_(18)O_(42)(Cl)]3.5H_2O[J].Chinese Journal of Structural Chemistry,2004,23(3). |
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| Authors: | ZHENG Shou-tian YANG Guo-Yu |
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| Abstract: | A novel two-dimensional compound Ni0.5(H2O)1.5{Ni(en)2}3V18O42(Cl)]3.5H2O 1 has been hydrothermally synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction analysis. Crystal data for 1: monoclinic, space group C2/c with a = 12.824(3), b = 27.873(6), c = 21.092(4) , b = 92.93(3), V = 7529(3) 3, Z = 4, Dc = 2.012 g/cm3, Mr = 2280.56, F(000) = 4476 and m = 3.092 mm-1. The final R and wR are 0.0769 and 0.1783, respectively for 4203 observed reflections with I>2s(I). The structure consists of V18O42(Cl)]7- clusters linked by trans- {Ni(en)2} groups into linear chains, while cis-{Ni(en)2} groups provide the cross-linking adjacent chains to form a two-dimensional structure. |
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| Keywords: | hydrothermal synthesis polyoxovanadate crystal structure vanadium cluster nickel |
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