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Synthesis,photochromism, and complex-forming ability of p-tosylaminobenzylideneaminospironaphthooxazine
Authors:L. D. Popov  I. N. Shcherbakov  V. A. Kogan  O. I. Kobeleva  T. M. Valova  V. A. Barachevsky  A. I. Shienok  L. S. Kol’tsova  O. Yu. Os’kina  N. L. Zaichenko
Affiliation:1.Southern Federal University,Rostov-on-Don,Russian Federation;2.Photochemistry Center,Russian Academy of Sciences,Moscow,Russian Federation;3.N. N. Semenov Institute of Chemical Physics,Russian Academy of Sciences,Moscow,Russian Federation
Abstract:New hybrid spirooxazine was synthesized from the 8′-amino-substituted spironaphtho-oxazine and 2-(p-tosylamino)benzaldehyde. Photochromism and the complex-forming ability toward Mg2+, Ba2+, La3+, and Tb3+ ions of the synthesized compound and initial 8′-amino-spironaphthooxazine were studied in comparison. The spectral kinetic differences in the photochromism and complex formation of these compounds were revealed.
Keywords:
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