IR spectroelectrochemical study on UVO2+ complex: first evidence for weakening of U[double bond]O bond strength in uranyl moiety with reduction from U(VI) to U(V) |
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| Authors: | Mizuoka Koichiro Ikeda Yasuhisa |
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| Institution: | Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8550, Japan. |
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| Abstract: | We have obtained the first evidence that the Udouble bond]O bond strength in uranyl moiety is weakened with the reduction from U(VI)O(2)(2+) to U(V)O(2)(+) from the IR spectroelectrochemical study on U(VI)O(2)(saloph)DMSO and U(V)O(2)(saloph)DMSO](-) (saloph = N,N'-disalicylidene-o-phenylenediaminate, DMSO = dimethyl sulfoxide) complexes with the thin layer electrode cell for IR measurements. |
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