| 溶剂热法制备纳米MnOOH |
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| 引用本文： | 陈琳,田俐,李帅,朱金良,吕数子.溶剂热法制备纳米MnOOH[J].化学研究,2011,22(1):53-57. |
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| 作者姓名： | 陈琳 田俐 李帅 朱金良 吕数子 |
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| 作者单位： | 1. 湖南科技大学,学生工作处,湖南,湘潭,411201
2. 湖南科技大学,材料科学与工程系,湖南,湘潭,411201 |
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| 基金项目： | 中南大学博士后基金，湖南科技大学博士启动基金，教育科研基金 |
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| 摘 要： | MnOOH在常温常压下为黑色固体粉末,经氧化或还原可制成电子工业中生产锰锌铁氧体软磁材料的重要原料.以KMnO4与MnSO4为原料,在水与正丙醇混合溶剂中反应制备了MnOOH纳米棒;采用X射线粉末衍射仪(XRD)、差热-热重(DTA-TG)分析系统、红外光谱仪(IR),以及扫描电镜(SEM)、透射电镜(TEM)、X射线...
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| 关 键 词： | 溶剂热法 纳米MnOOH 制备 |
Synthesis of nanosized MnOOH via solvothermal route |
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| CHEN Lin,TIAN Li,LI Shuai,ZHU Jin-liang,L Shu-zi.Synthesis of nanosized MnOOH via solvothermal route[J].Chemical Research,2011,22(1):53-57. |
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| Authors: | CHEN Lin TIAN Li LI Shuai ZHU Jin-liang L Shu-zi |
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| Institution: | CHEN Lin,TIAN Li,LI Shuai,ZHU Jin-liang,L(U) Shu-zi |
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| Abstract: | Black powder MnOOH can be oxidized or reduced to generate raw materials for producing zinc manganese iron oxide magnetic ferrite materials in electronics industry.KMnO4 and MnSO4 were used as raw materials to synthesize MnOOH nanorods in mixed solvent of water and propanol.The phase,structure,morphology and composition of the products were analyzed by means of X-ray diffraction,differential thermal analysis,infrared spectrometry,scanning electron microscopy,transmission electron microscopy,and energy dispersive spectrometry.The influence of experiment conditions,including reaction temperature,time and solvent,on the phase and shape of nanosized MnOOH were studied.Results show that as-prepared MnOOH nanorods with a length of several microns and diameter of 50 nm could be obtained via solvothermal route at a temperatures of 140-220 ℃ and time of 6-12 h.Propanol played a significant role in the formation of nano-sized MnOOH. |
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| Keywords: | solvothermal method nanosized MnOOH preparation |
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