Textural changes in alumina coked by toluene cracking in fluidized bed |
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Authors: | A Miloudi D Duprez M Bastick and J Bastick |
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Institution: | (1) Laboratoire de Physico-Chimie Industrielle, 1, rue Grandville, 54042 Nancy, Cedex, France;(2) Present address: Laboratoire de Catalyse Organique, 40, Avenue Recteur Pineau, 86022 Poitiers, Cedex, France |
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Abstract: | The texture of an alumina coked at 873–923 K has been studied by specific area measurements and determination of pore size distributions. Two opposite textural changes have been observed: a strong plugging of the microporosity (r=18–30 Å) and an increase of the porous volume and surface area of the larger porosity (r=30–1000 Å).
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![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![tscy](/content/x4652v1t820g4548/xxlarge1094.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![fcy](/content/x4652v1t820g4548/xxlarge1092.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![chcy](/content/x4652v1t820g4548/xxlarge1095.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![kcy](/content/x4652v1t820g4548/xxlarge1082.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![vcy](/content/x4652v1t820g4548/xxlarge1074.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![khcy](/content/x4652v1t820g4548/xxlarge1093.gif) 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![lcy](/content/x4652v1t820g4548/xxlarge1083.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![yucy](/content/x4652v1t820g4548/xxlarge1102.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![ycy](/content/x4652v1t820g4548/xxlarge1099.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![zcy](/content/x4652v1t820g4548/xxlarge1079.gif) ![mcy](/content/x4652v1t820g4548/xxlarge1084.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![tcy](/content/x4652v1t820g4548/xxlarge1090.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![kcy](/content/x4652v1t820g4548/xxlarge1082.gif) ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![tcy](/content/x4652v1t820g4548/xxlarge1090.gif) ![ucy](/content/x4652v1t820g4548/xxlarge1091.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) : ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![lcy](/content/x4652v1t820g4548/xxlarge1083.gif) ![softcy](/content/x4652v1t820g4548/xxlarge1100.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![acy](/content/x4652v1t820g4548/xxlarge1072.gif) ![zcy](/content/x4652v1t820g4548/xxlarge1079.gif) ![acy](/content/x4652v1t820g4548/xxlarge1072.gif) ![kcy](/content/x4652v1t820g4548/xxlarge1082.gif) ![ucy](/content/x4652v1t820g4548/xxlarge1091.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![kcy](/content/x4652v1t820g4548/xxlarge1082.gif) ![mcy](/content/x4652v1t820g4548/xxlarge1084.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![kcy](/content/x4652v1t820g4548/xxlarge1082.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) (r=18–30 Å) ![ucy](/content/x4652v1t820g4548/xxlarge1091.gif) ![vcy](/content/x4652v1t820g4548/xxlarge1074.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![lcy](/content/x4652v1t820g4548/xxlarge1083.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![chcy](/content/x4652v1t820g4548/xxlarge1095.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![bcy](/content/x4652v1t820g4548/xxlarge1073.gif) ![softcy](/content/x4652v1t820g4548/xxlarge1100.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![mcy](/content/x4652v1t820g4548/xxlarge1084.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![lcy](/content/x4652v1t820g4548/xxlarge1083.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![shchcy](/content/x4652v1t820g4548/xxlarge1097.gif) ![acy](/content/x4652v1t820g4548/xxlarge1072.gif) ![dcy](/content/x4652v1t820g4548/xxlarge1076.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![vcy](/content/x4652v1t820g4548/xxlarge1074.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![khcy](/content/x4652v1t820g4548/xxlarge1093.gif) ![ncy](/content/x4652v1t820g4548/xxlarge1085.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![tcy](/content/x4652v1t820g4548/xxlarge1090.gif) ![bcy](/content/x4652v1t820g4548/xxlarge1073.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![lcy](/content/x4652v1t820g4548/xxlarge1083.gif) ![softcy](/content/x4652v1t820g4548/xxlarge1100.gif) ![shchcy](/content/x4652v1t820g4548/xxlarge1097.gif) ![iecy](/content/x4652v1t820g4548/xxlarge1077.gif) ![pcy](/content/x4652v1t820g4548/xxlarge1087.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![rcy](/content/x4652v1t820g4548/xxlarge1088.gif) ![icy](/content/x4652v1t820g4548/xxlarge1080.gif) ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![tcy](/content/x4652v1t820g4548/xxlarge1090.gif) ![ocy](/content/x4652v1t820g4548/xxlarge1086.gif) ![scy](/content/x4652v1t820g4548/xxlarge1089.gif) ![tcy](/content/x4652v1t820g4548/xxlarge1090.gif) ![softcy](/content/x4652v1t820g4548/xxlarge1100.gif) (r=30–100 Å).
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