The kinetics of acid-catalyzed decomposition of decanepersulfonic acid |
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| Authors: | R. N. Zaripov A. A. Mukhametzyanova R. L. Safiullin V. D. Komissarov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | The kinetics of thermal decomposition of decanepersulfonic acid (RSO2OOH, R=C10H21) in CCl4 in the presence of cyclohexanesulfonic and trifluoroacetic acids at 323–343 K was studied. The reaction has an autocatalytic character. The kinetics of consumption of the persulfonic acid is described by the equation-d[RSO2OOH]/dt=k 1[RSO2OOH]+k 2[RSO2OOH]·[HX]. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 202–203, January, 1999. |
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| Keywords: | decanepersulfonic acid decomposition acid catalysis kinetics |
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