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Reactions of (difluoroamino)trinitromethane with nucleophilic reagents |
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| Authors: | Khisamutdinov G. Kh. Shevelev S. A. |
| Affiliation: | (1) State Research Institute !["ldquo"]("/content/k52732783368x504/xlarge8220.gif") Kristall!["rdquo"]("/content/k52732783368x504/xlarge8221.gif") , 6 ul. Zelenaya, 606007 Dzerzhinsk, Nizhnii Novgorod Region, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119992 Moscow, Russian Federation |
| Abstract: | Reactions of F2NC(NO2)3 with metal fluorides (KF and CsF) in DMF yield a substitution product of the fluorine atom for one nitro group, F2NC(NO2)2F. The reaction of F2NC(NO2)3 with LiBr in ethanol or DMF affords Br(NO2)C=NF rather than the expected bromo derivative F2NC(NO2)2Br. |
| Keywords: | (difluoroamino)trinitromethane (difluoroamino)fluorodinitromethane bromonitro(N-fluoroimino)methane substitution reaction |
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