Reaction of nitrosonium trifluoromethanesulfonate with fluoroolefins and some properties of the resulting products |
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| Authors: | V. S. Savostin I. I. Krylov A. P. Kutepov A. I. Rapkin A. V. Fokin |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | The reaction of nitrosonium trifluoromethanesulfonate with fluoroolefins resulted in  -nitrosofluoroalkyltrifluoromethanesulfonates, the corresponding 1,2-oxazetidines, and nitrosofluoro polymers. The nitroso compounds, under the effect of nitrogen tetroxide, were oxidized to -nitrofluoroalkyltrifluoromethanesulfonates. Pyrolysis of the oxazetidines and nitrosofluoro polymers resulted in the synthesis of fluoroazomethines containing the CF3-SO2O group.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1851–1855, August, 1990. |
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