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Stereoselective synthesis of (Z)-γ-cyano-β-perfluoroalkyl-β,γ-unsaturated esters |
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| Authors: | Yanchang Shen Jiahong Ni |
| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, PR China |
| Abstract: | (Z)-γ-Cyano-β-perfluoroalkyl-β,γ-unsaturated esters have been synthesized by the reaction of perfluoroacylated phosphonates with organozinc reagent in 50-71% (three steps) yields. |
| Keywords: | γ-Cyano-β-perfluoroalkyl-β γ-unsaturated ester β γ-Unsaturated ester Perfluoroacylated phosphonates Stereoselective synthesis |
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