Enol tosylates as viable partners in Pd-catalyzed cross-coupling reactions |
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| Authors: | Steinhuebel Dietrich Baxter Jenny M Palucki Michael Davies Ian W |
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| Institution: | Department of Process Research, Merck & Co., Inc., P.O. Box 2000, Rahway, New Jersey 07065, USA. dietrich_steinhuebel@merck.com |
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| Abstract: | reaction: see text] Herein we demonstrate functionalized enol tosylates to be robust substrates that undergo Suzuki-Miyaura, Sonogashira, and Stille cross-coupling reactions to provide stereodefined trisubstituted unsaturated esters. |
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