Catalytic oxidation of monosubstituted phenols by hydrogen peroxide |
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| Authors: | Yu V Mitnik D O Oludipe I Yu Litvintsev and V N Sapunov |
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| Institution: | (1) Moscow Institute of Chemical Technology, Miusskaya Square 9, A-47 Moscow, USSR |
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| Abstract: | Studies of kinetic peculiarities in hydroxylation of phenols by H2O2 in the presence of ferric sulfate have revealed general regularities of this process. A scheme of this process is suggested accounting for the stepwise conversion of Fe3+ into various complex forms. The reaction is suggested to take place in the coordination sphere of Fe3+.
                     H2O2     .     .   ,  Fe3+ .
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