Synthesis and structure of the hexameric,dodecanuclear metallamacrocycle [(5-methyl-3-phenylpyrazole)2Zn2(OCH2CH2S)]6 |
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Authors: | Puerta David T Cohen Seth M |
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Institution: | Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California, USA. |
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Abstract: | A metallamacrocycle containing twelve Zn2+ ions, making it the largest member of a family of pyrazole-bridged cyclic metal clusters, has been synthesized and structurally characterized from the reaction of Zn(ClO4)2] with 5-methyl-3-phenylpyrazole, 2-mercaptoethanol, and NaOH. |
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