Charge assisted chiral hybrid H-bonded molecular networks |
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Authors: | Ferlay Sylvie Holakovsky Roman Hosseini Mir Wais Planeix Jean-Marc Kyritsakas Nathalie |
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Affiliation: | Laboratoire de Chimie de Coordination Organique, Service Commun des Rayons X, Université Louis Pasteur, F-67000 Strasbourg, France. |
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Abstract: | The co-crystallisation of [Fe(CN)5NO]2- and cyclic achiral 1(2+) and chiral 2(2+) or 3(2+) bisamidinium tectons leads in the crystalline phase to the formation of 1-D H-bonded achiral and chiral molecular networks respectively. In all cases, the network is formed by mutual bridging of the anionic and cationic units through a chelate mode of H-bonding. |
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