Hydrotelluration of aminoalkynes |
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| Authors: | Zeni Gilson Barros Olga Soares do Rego Moro Angélica Venturini Braga Antonio Luiz Peppe Clovis |
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| Institution: | Departamento de Química, Laboratório de Bioquímica Toxicológica, UFSM-97105-900, Santa Maria, RS, Brazil. gzeni@quimica.ufsm.br |
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| Abstract: | Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the amino group substituent. |
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