Determination of the rate constant for the reaction NH3 + OH → NH2 + H2O |
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| Authors: | N Fujii H Miyama T Asaba |
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| Institution: | Department of Materials Science and Technology, The Technological University of Nagaoka, Kamitomioka, Nagaoka City, Niigata, Japan 949-54;Department of Reaction Chemistry, University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo, Japan 113 |
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| Abstract: | The rate constant for the reaction NH3 + OH → NH2 + H2O was determined by the comparison of the calculated induction period data with experiments by the shock tube technique in the range 1360–1840 K, for NH3-H2-O2-Ar mixtures. The rate constants can be represented by the expression k = 1012.49±0.04exp(?1.95±0.15) kcal/,RT] cm3 mol?1 s?1. |
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