Improved spin hamiltonian parameters for Mn2+ determined by EPR at zero magnetic field |
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| Authors: | Richard Bramley Steven J Strach |
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| Institution: | Research School of Chemistry, Australian National University, Canberra, A.C.T. 3600, Australia |
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| Abstract: | EPR has been studied at zero magnetic field for high-spin Mn2+ in MgSO4·7H2O and NH4Cl. Significant differences have been found between high-field EPR spin hamiltonmn parameters in the literature and those necessary to fit the complex zero-field spectra. Sources of the discrepancies are discussed in relation to the Mn2+ systems and more generally |
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