Anomalous electronic energy partitioning in Mg*(3p) + (F2, Cl2) and Ca*(3P) + Cl2 reactions |
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| Authors: | Andrzej Kowalski Michael Menzinger |
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| Affiliation: | Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 1A1 |
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| Abstract: | Absolute cross sections were measured for beam attenuation, MX+(1Σg+) chemiionization and MX(A2Π) chemiluminescence. The latter disagree strikingly with predictions based on adiabatic correlations. Information theoretic analysis shows some channels to be statistically, other highly non-statistically populated. A qualitative MO model is in accord with these findings. |
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| Keywords: | To whom correspondence should be addressed |
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