Reactions of CFBr studied by laser-induced fluorescence |
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| Authors: | JR Purdy BA Thrush |
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| Institution: | Department of Physical Chemistry, University of Cambridge, Cambridge CB2 1EP, UK |
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| Abstract: | Laser-induced fluorescence has been used to study reactions of CFBr radicals in a discharge-flow system. Arrhenius expressions of (1.9 ± 0.6) ξ 10?12 exp(?762± 92/T) and (1.4 ± 0.3) ξ 10?12 exp(?533 ± 62/T) cm3 molecule ?1s?1 for their reactions with Cl2 and Br2 respectively. Upper limits were obtained for the rate of reaction of CFBr with O2 and F2CCFBr. |
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