Kinetic isotope effects in the reaction H + C2H4 → C2H5 |
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| Authors: | Ko-Ichi Sugawara Kiyoshi Okazaki Shin Sato |
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| Institution: | Department of Applied Physics, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152, Japan |
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| Abstract: | The high-pressure limiting rate constants of the reactions between H or D atoms and three isotopic ethylenes have been measured in the temperature range 206–461 K. Practically no isotope effects due to the differences between the ethylenes could be observed. This result does not agree with the prediction recently made by the activated complex theory. |
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