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The multiphoton ionization spectrum of toluene in a supersonic free jet: internal rotation of the methyl group |
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| Authors: | Jun-ichi Murakami Mitsuo Ito Koji Kaya |
| Affiliation: | Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980, Japan |
| Abstract: | The S1← So electronic transitions of toluene involving also some internal rotational levels were observed for the first time in the multiphoton ionization spectrum in a supersonic jet. A large population in several low-lying internal rotational levels and a strong coupling between electronic motion and the internal rotation are suggested. |
| Keywords: | Present address: Department of Chemistry Faculty of Science and Engineering Keio University Hiyoshi-machi Kohoku-ku Yokohama Japan. |
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