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General theory of vibrational mode mixing and frequency shifts in resonance raman scattering
Authors:D.L. Tonks  J.B. Page
Affiliation:Department of Physics, Arizona State University, Tempe, Arizona 85281, USA
Abstract:A general formalism is given for treating vibrational mode mixing, frequency shifts, and atomic equilibrium position shifts under electronic excitation in resonance Raman scattering. The theory is exact for first-order scattering at T = 0 K for all linear and quadratic electron-phonon coupling strengths. Numerical results illustrating mode mixing are presented.
Keywords:Present address: Chemical Research Institute of Nonaqueous Solutions   Tohoku University   Sendai   980   Japan.
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