Electron transfer reactions in photoelectron emission spectroscopy of aqueous solutions |
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Authors: | Kathrin Von Burg Paul Delahay |
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Affiliation: | Department of Chemistry, New York University, New York, New York 10003, USA |
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Abstract: | Lowering of the emission yield of anions by certain cations (e.g. H+, Fe2+, Ba2+) is interpreted as the result of electron transfer between anions and cations. An equation is derived which predicts the exponential dependence of the yield on concentration of electron acceptor at constant emitter concentration. This equation is verified by experiment. |
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