Vibrational energy exchange between CO(v=1) and 14N2 and CO(v=1) and 15N2XXXured to 60 k in the gas phase |
| |
| Authors: | E.T. Handler E.A. Gregory R.M. Siddles C.J.S.M. Simpson |
| |
| Affiliation: | Physical Chemistry Laboratory, Oxford OX1 3QZ,UK |
| |
| Abstract: | Laser fluorescence technique has been used to measure (VV) exchange rates between CO(v = 1) and 14N2 and 15N2 XXX At 65 K exchange to 15N2 has 65 times the higher rate constant. Comparison with data for (VV) exchange in liquid 2 shows that the isolated binary collision theory does not hold for the case of CO(v = 1) and 14N2. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
