Magnetic circular dichroism of azuleno[1,2-b]azulene derivatives |
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| Authors: | Akio Tajiri Masahiro Hatano Takashi Toda Norihiko Shimazaki Toshio Mukai |
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| Institution: | Chemical Research Institute of Non-aqueous Solutions, Tohoku University, Sendai 980, Japan;Department of Chemistry, Faculty of Science, Tohoku University, Sendai 980, Japan |
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| Abstract: | Both 6,12-diphenylazuleno1,2-b] azulene and 6,12-di-p-bromophenylazuleno 1,2-b] azulene exhibit similar absorption and MCD spectra. PPP calculations reproduce the observed absorption and MCD spectra. The phenyl and p-bromophenyl groups are considered to present no obstacle in investigating the spectroscopic behavior of azuleno1,2-b] azulene. |
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