Synthesis and Structural Studies of Group 2B Transition Metal Complexes with the Bulky Nitrogen Ligand Bis[ N-(2,6-diisopropylphenyl) imino]acenaphthene |
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Authors: | Usama El-Ayaan |
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Abstract: | Group 2B transition metal complexes of bisN-(2,6-diisopropylphenyl)imino]acenaphthene (o,o-iPr2C6H3-BIAN), namely, Hg(o,o-iPr2C6H3-BIAN)Cl2] (1), Zn(o,o-iPr2C6H3-BIAN)2](ClO4)2 (2), and Cd(o,o-iPr2C6H3-BIAN)2](ClO4)2 (3) have been synthesized and characterized. In complexes 2 and 3, IR, NMR, and conductivity measurements confirm the coordination of two (o,o-iPr2C6H3-BIAN) ligands to the metal center with two discrete perchlorate anions. X-Ray crystal structure of 1 indicates a distorted tetrahedral geometry with two nitrogen atoms from (o,o-iPr2C6H3-BIAN) ligand and two chloride atoms coordinating to the Hg(II) center. |
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