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Synthesis and absolute configuration of (−)-serantrypinone |
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| Authors: | David J. Hart Gabriel Oba |
| Affiliation: | Department of Chemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210, USA |
| Abstract: | A synthesis of (−)-serantrypinone (3) has been achieved from l-tryptophan. A key reaction involves the transformation of a selenoxide to an acetate via trapping of a presumed intermediate in a seleno-Pummerer reaction. |
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