Tandem asymmetric conjugate addition-enolacetates formation of enantiomerically enriched zinc and aluminium enolates |
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Authors: | Magali Vuagnoux-d&rsquo Augustin |
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Affiliation: | Department of Organic Chemistry, University of Geneva, 30, Quai Ernest Ansermet, 1211 Geneva 4, Switzerland |
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Abstract: | The metal enolates, resulting from the copper-catalyzed enantioselective conjugate addition of organometallic reagents (Et2Zn or R3Al) to cyclic and acyclic enones are quantitatively trapped as enolacetates with acetic anhydride. |
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Keywords: | Michael addition Copper Enolacetate |
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