Formation of acetaldehyde via photocarbonylation of methane with CO |
| |
| Authors: | R Kazimerczuk M Borowiak K Zwoliński A Trzeciak JCz Dobrowolski |
| |
| Institution: | a Industrial Chemistry Research Institute, Rydygiera 8, 01-793 Warszawa, Poland
b Faculty of Chemistry, University of Wroc?aw, F. Joliot-Curie 14, 50-383 Wroc?aw, Poland |
| |
| Abstract: | Direct photocarbonylation of methane to give acetaldehyde occurred when a mixture of methane and CO dissolved in benzene was subjected to UV irradiation at λ < 290 nm. The reaction was accelerated by rhodium RhCl(CO)(PR3)2 complexes, where R = alkyl, Ph, or OPh. |
| |
| Keywords: | Methane carbonylation Acetaldehyde Rhodium complexes |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
